Volume 26
Main Index

Issue 01

Masthead DOI: 10.1021/ar00025a700

X-ray absorption edge studies of the electronic structure of metal catalysts John H. Sinfelt, George D. Meitzner pp 1–6 DOI: 10.1021/ar00025a001

The molecular anatomy of a calcium binding protein Sture Forsen, Johan Koerdel, Thomas Grundstroem, Walter J. Chazin pp 7–14 DOI: 10.1021/ar00025a002

Biosynthesis of vitamin B12 Alan R. Battersby pp 15–21 DOI: 10.1021/ar00025a003

The coordination polymerization of silanes to polysilanes by a ".sigma.-bond metathesis" mechanism. Implications for linear chain growth T. Don Tilley pp 22–29 DOI: 10.1021/ar00025a004

Issue 02

Transition-state spectroscopy via negative ion photodetachment Daniel M. Neumark pp 33–40 DOI: 10.1021/ar00026a001

Cp'M(NO)R2: 16-electron piano-stool molecules of molybdenum and tungsten Peter Legzdins, John E. Veltheer pp 41–48 DOI: 10.1021/ar00026a002

Alkali halide nanocrystals Robert L. Whetten pp 49–56 DOI: 10.1021/ar00026a003

The current view of dynamic change within cyclooctatetraenes Leo A. Paquette pp 57–62 DOI: 10.1021/ar00026a004

Effect of molecular architecture on polymer-surface adsorption Anna C. Balazs pp 63–68 DOI: 10.1021/ar00026a005

Is the transition state indeed intermediate between reactants and products? The Michael addition reaction as a case study Shmaryahu Hoz pp 69–74 DOI: 10.1021/ar00026a006

Ethical Guidelines to Publication of Chemical Research pp 75–76 DOI: 10.1021/ar00026a600

Issue 03

Masthead DOI: 10.1021/ar00027a700

Voltammetry for the future Janet Osteryoung pp 77–83 DOI: 10.1021/ar00027a001

New perspectives on carbene rearrangements: migratory aptitudes, bystander assistance, and geminal efficiency Alex Nickon pp 84–89 DOI: 10.1021/ar00027a002

The 15 years of reductive coupling: what have we learned? Edmund M. Carnahan, John D. Protasiewicz, Stephen J. Lippard pp 90–97 DOI: 10.1021/ar00027a003

Targeted chemical nucleases David S. Sigman, Thomas W. Bruice, Abhijit Mazumder, Christopher L. Sutton pp 98–104 DOI: 10.1021/ar00027a004

Directions for environmentally biodegradable polymer research Graham Swift pp 105–110 DOI: 10.1021/ar00027a005

New vistas in zeolite and molecular sieve catalysis Mark E. Davis pp 111–115 DOI: 10.1021/ar00027a006

Chiral methyl groups: small is beautiful Heinz G. Floss, Sungsook Lee pp 116–122 DOI: 10.1021/ar00027a007

Molecular solvation in atomic clusters studied by means of molecular beam infrared spectroscopy Sandeep Goyal, David L. Schutt, Giacinto Scoles pp 123–130 DOI: 10.1021/ar00027a008

Issue 04

Masthead DOI: 10.1021/ar00028a700

Methodological advances in protein NMR Ad Bax, Stephan Grzesiek pp 131–138 DOI: 10.1021/ar00028a001

Sterol metabolism in insects: dealkylation of phytosterol to cholesterol Nobuo Ikekawa, Masuo Morisaki, Yoshinori Fujimoto pp 139–146 DOI: 10.1021/ar00028a002

Quantitative structure-activity relationships and the unnamed science Corwin Hansch pp 147–153 DOI: 10.1021/ar00028a003

The azido human methemoglobin controversy: is there evidence for a quaternary structure-spin state linkage or not? Michael J. Kelleher pp 154–159 DOI: 10.1021/ar00028a004

Taxol and taxotere: discovery, chemistry, and structure-activity relationships Daniel Guenard, Francoise Gueritte-Voegelein, Pierre Potier pp 160–167 DOI: 10.1021/ar00028a005

The stability of three-body atomic and molecular ions Edward A. G. Armour, William Byers Brown pp 168–173 DOI: 10.1021/ar00028a006

Beyond transition-state theory: a rigorous quantum theory of chemical reaction rates William H. Miller pp 174–181 DOI: 10.1021/ar00028a007

Enzyme-catalyzed organic synthesis: practical routes to aza sugars and their analogs for use as glycoprocessing inhibitors Gary C. Look, Christopher H. Fotsch, Chi Huey Wong pp 182–190 DOI: 10.1021/ar00028a008

Synthetic peptides as models for ion channel proteins Karin S. Akerfeldt, Jim D. Lear, Zelda R. Wasserman, Laura A. Chung, William F. DeGrado pp 191–197 DOI: 10.1021/ar00028a009

Molecular mimicry of photosynthetic energy and electron transfer Devens Gust, Thomas A. Moore, Ana L. Moore pp 198–205 DOI: 10.1021/ar00028a010

Enzyme reactivity from an organic perspective Fredric M. Menger pp 206–212 DOI: 10.1021/ar00028a011

Bare transition metal atoms in the gas phase: reactions of M, M+, and M2+ with hydrocarbons James C. Weisshaar pp 213–219 DOI: 10.1021/ar00028a012

Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations Peter C. Ford, Arnd Vogler pp 220–226 DOI: 10.1021/ar00028a013

Mechanisms of pericyclic reactions: the role of quantitative theory in the study of reaction mechanisms. [Erratum to document cited in CA117(23):233125u] Michael J. S. Dewar, Caoxian Jie pp 226–226 DOI: 10.1021/ar00028a014

Issue 05

Masthead DOI: 10.1021/ar00029a700

Solution structures of lithium dialkylamides and related N-lithiated species: results from lithium-6-nitrogen-15 double labeling experiments David B. Collum pp 227–234 DOI: 10.1021/ar00029a001

Turing structures in simple chemical reactions Istvan Lengyel, Irving R. Epstein pp 235–240 DOI: 10.1021/ar00029a002

Microbial iron chelators as drug delivery agents: the rational design and synthesis of siderophore-drug conjugates Marvin J. Miller, Francois Malouin pp 241–249 DOI: 10.1021/ar00029a003

The principle of maximum hardness Ralph G. Pearson pp 250–255 DOI: 10.1021/ar00029a004

Absolute hardness: unifying concept for identifying shells and subshells in nuclei, atoms, molecules, and metallic clusters Robert G. Parr, Zhongxiang Zhou pp 256–258 DOI: 10.1021/ar00029a005

Ferromagnetic spin alignment in molecular systems: an orbital approach Christian Kollmar, Olivier Kahn pp 259–265 DOI: 10.1021/ar00029a006

A dozen years of retro-inverso peptidomimetics Michael Chorev, Murray Goodman pp 266–273 DOI: 10.1021/ar00029a007

Synthetic gene-transfer vectors Jean Paul Behr pp 274–278 DOI: 10.1021/ar00029a008

Reductive elimination of hydrogen chloride from chloro hydrido transition metal complexes: an efficient and simple method for generation of electron-rich, coordinatively unsaturated, reactive intermediates Vladimir V. Grushin pp 279–286 DOI: 10.1021/ar00029a009

Bond energies in solution from electrode potentials and thermochemical cycles. A simplified and general approach Danial D. M. Wayner, Vernon D. Parker pp 287–294 DOI: 10.1021/ar00029a010

Issue 06

Masthead DOI: 10.1021/ar00030a700

Gas-phase analogs of cage effects David J. McAdoo, Thomas Hellman Morton pp 295–302 DOI: 10.1021/ar00030a001

Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide Ayusman Sen pp 303–310 DOI: 10.1021/ar00030a002

"Super" phanes Rolf Gleiter, Detlef Kratz pp 311–318 DOI: 10.1021/ar00030a003

Glycobiology: an expanding research area in carbohydrate chemistry Akira Kobata pp 319–324 DOI: 10.1021/ar00030a004

Kinetic and mechanistic effects of ease of carbon-nitrogen bond breaking in amide hydrolysis. The mechanisms of hydrolysis of N-acylimidazoles and N-acylbenzimidazoles Thomas H. Fife pp 325–331 DOI: 10.1021/ar00030a005

Vectorial chemistry in bioenergetics: cytochrome c oxidase as a redox-linked proton pump Bo G. Malmstroem pp 332–338 DOI: 10.1021/ar00030a006

Chiral semicorrins and related nitrogen heterocycles as ligands in asymmetric catalysis Andreas Pfaltz pp 339–345 DOI: 10.1021/ar00030a007

Studies of organic di-, oligo-, and polyradicals by means of their bulk magnetic properties Hiizu Iwamura, Noboru Koga pp 346–351 DOI: 10.1021/ar00030a008

Issue 07

Masthead DOI: 10.1021/ar00031a700

Multilayer argon films on graphite: structural and melting properties J. Z. Larese pp 353–360 DOI: 10.1021/ar00031a001

Bioorganometallic chemistry: a future direction for transition metal organometallic chemistry? Gerard Jaouen, Anne Vessieres, Ian S. Butler pp 361–369 DOI: 10.1021/ar00031a002

Selective electrophilic activation of alkanes Jean Sommer, Jozef Bukala pp 370–376 DOI: 10.1021/ar00031a003

Spectroscopy and imaging using the photon scanning-tunneling microscope S. L. Sharp, R. J. Warmack, J. P. Goudonnet, I. Lee, T. L. Ferrell pp 377–382 DOI: 10.1021/ar00031a004

Metal clusters in zeolites: an intriguing class of catalysts Wolfgang M. H. Sachtler pp 383–387 DOI: 10.1021/ar00031a005

Masthead DOI: 10.1021/ar00031a700

Issue 08

Masthead DOI: 10.1021/ar00032a700

Editorial - Chemistry and Immunology: A Powerful Combination Barbara Baird, Fred McLafferty pp 389–390 DOI: 10.1021/ar00032a600

Antibody catalysis of difficult chemical transformations Peter G. Schultz, Richard A. Lerner pp 391–395 DOI: 10.1021/ar00032a001

Reaction mechanisms displayed by catalytic antibodies Jon D. Stewart, Louis J. Liotta, Stephen J. Benkovic pp 396–404 DOI: 10.1021/ar00032a002

Monoclonal antibodies from combinatorial libraries Dennis R. Burton pp 405–411 DOI: 10.1021/ar00032a003

The cell cycle, signal transduction, and immunophilin-ligand complexes Stuart L. Schreiber, Mark W. Albers, Eric J. Brown pp 412–420 DOI: 10.1021/ar00032a004

Antibody structure David R. Davies, Susan Chacko pp 421–427 DOI: 10.1021/ar00032a005

Structural mapping of IgE-Fc.epsilon.RI, an immunoreceptor complex Barbara Baird, Yi Zheng, David Holowka pp 428–434 DOI: 10.1021/ar00032a006

Structural aspects and chemistry of T cell receptor recognition of antigen-MHC complexes Edwin P. Rock, Mark M. Davis pp 435–441 DOI: 10.1021/ar00032a007

The kinetics of peptide reactions with class II major histocompatibility complex membrane proteins Stephan N. Witt, Harden M. McConnell pp 442–448 DOI: 10.1021/ar00032a008

CD4: structure and interactions of an immunoglobulin superfamily adhesion molecule Stephen C. Harrison pp 449–453 DOI: 10.1021/ar00032a009

Issue 09

Masthead DOI: 10.1021/ar00033a700

Electron transfer, bond breaking, and bond formation Jean Michel Saveant pp 455–461 DOI: 10.1021/ar00033a001

Structural, mechanistic, and theoretical aspects of chelation-controlled carbonyl addition reactions Manfred T. Reetz pp 462–468 DOI: 10.1021/ar00033a002

Expanding roles for templates in synthesis Sally Anderson, Harry L. Anderson, Jeremy K. M. Sanders pp 469–475 DOI: 10.1021/ar00033a003

Stereoelectronic effects in the formation of 5- and 6-membered rings: the role of Baldwin's rules C. David Johnson pp 476–482 DOI: 10.1021/ar00033a004

Atranes: new examples with unexpected properties John G. Verkade pp 483–489 DOI: 10.1021/ar00033a005

Strategy of research on supported metal catalysts. Problems of structure-sensitive reactions in the gas phase Geoffrey C. Bond pp 490–495 DOI: 10.1021/ar00033a006

Paradigms and algorithms for controlling molecular motion Daniel Neuhauser, Herschel Rabitz pp 496–501 DOI: 10.1021/ar00033a007

Photochemistry and photophysics of trans-stilbene and related alkenes in surfactant assemblies David G. Whitten pp 502–509 DOI: 10.1021/ar00033a008

From equilibrium acidites to radical stabilization energies Frederick G. Bordwell, Xian Man Zhang pp 510–517 DOI: 10.1021/ar00033a009

New perspectives on carbene rearrangements: migratory aptitudes, bystander assistance, and geminal efficiency. [Erratum to document cited in CA118(15):146952p] Alex Nickon pp 518–518 DOI: 10.1021/ar00033a010

Issue 10

Masthead DOI: 10.1021/ar00034a700

Chromium complexes derived from molecular oxygen Andreja Bakac, James H. Espenson pp 519–523 DOI: 10.1021/ar00034a001

Cubane-type clusters as potential models for inorganic solid surfaces Kiyoshi Isobe, Atsushi Yagasaki pp 524–529 DOI: 10.1021/ar00034a002

Photochemistry in organized and confining media: a model Richard G. Weiss, V. Ramamurthy, George S. Hammond pp 530–536 DOI: 10.1021/ar00034a003

Polymer-controlled drug delivery systems Robert Langer pp 537–542 DOI: 10.1021/ar00034a004

Zinc: biological functions and coordination motifs Bert L. Vallee, David S. Auld pp 543–551 DOI: 10.1021/ar00034a005

Antibody catalysis of carbon-carbon bond formation and cleavage Donald Hilvert pp 552–558 DOI: 10.1021/ar00034a006

Plant cell culture combined with chemistry: a powerful route to complex natural products James P. Kutney pp 559–566 DOI: 10.1021/ar00034a007

Issue 11

Masthead DOI: 10.1021/ar00035a700

Dynamics of antibodies on planar model membranes Nancy L. Thompson, Claudia L. Poglitsch, Melanie M. Timbs, Mary Lee Pisarchick pp 567–573 DOI: 10.1021/ar00035a001

Tellurometalates Mohammad Ansari, Jonathan M. McConnachie, James A. Ibers pp 574–578 DOI: 10.1021/ar00035a002

Transition metal promoted higher-order cycloaddition reactions in organic synthesis James H. Rigby pp 579–585 DOI: 10.1021/ar00035a003

Multiple metal-metal bonds in 4d and 5d metal-porphyrin dimers James P. Collman, Hilary J. Arnold pp 586–592 DOI: 10.1021/ar00035a004

The molecular electric quadrupole moment and solid-state architecture Jeffrey H. Williams pp 593–598 DOI: 10.1021/ar00035a005

Use of calculated quantum chemical properties as surrogates for solvatochromic parameters in structure-activity relationships Christopher J. Cramer, George R. Famini, Alfred H. Lowrey pp 599–605 DOI: 10.1021/ar00035a006

Additions and Corrections - Cover Photo Error pp 606–606 DOI: 10.1021/ar00035a600

Issue 12

Masthead DOI: 10.1021/ar00036a700

Heightened selectivity in aromatic nitrations and chlorinations by the use of solid supports and catalysts Lionel Delaude, Pierre Laszlo, Keith Smith pp 607–613 DOI: 10.1021/ar00036a001

Aggregation of globular proteins Linda R. De Young, Anthony L. Fink, Ken A Dill pp 614–620 DOI: 10.1021/ar00036a002

Modeling solutions containing specific interactions Charles A. Eckert, Diane L. Bergmann, David L. Tomasko, Michael P. Ekart pp 621–627 DOI: 10.1021/ar00036a003

The transition metal-carbonyl bond Ernest R. Davidson, Kathryn L. Kunze, Francisco B. C. Machado, Subhas J. Chakravorty pp 628–635 DOI: 10.1021/ar00036a004

Liquid interfaces Kenneth B. Eisenthal pp 636–643 DOI: 10.1021/ar00036a005

Structure and function of the DNA-binding domain of the glucocorticoid receptor and other members of the nuclear receptor supergene family Torleif Haerd, Jan Aake Gustafsson pp 644–650 DOI: 10.1021/ar00036a006